Two-step access to bis-meso-perfluoroalkyl-corroles towards meso-perfluoroacyl-ABC-corroles

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datacite.alternateIdentifier.citationOrganic and Biomolecular Chemistry, 22 (10), 1997-1993, 2024
datacite.alternateIdentifier.doi10.1039/d4ob00191e
datacite.alternateIdentifier.issn1477-0539
datacite.creatorJulliard, Paul Gabriel
datacite.creatorPascal, Simon
datacite.creatorSiri, Olivier
datacite.creatorGiorgi, Michel
datacite.creatorCortés-Arriagada, Diego
datacite.creatorSanhueza, Luís Manuel
datacite.creatorCanard, Gabriel
datacite.date2024
datacite.rightsAcceso abierto
datacite.subjectBenzaldehyde
datacite.subjectAcid-catalyzed Condensation
datacite.subjectAlkyl Substituent
datacite.subjectBasic Hydrolysis
datacite.subjectCorroles
datacite.subjectDipyrromethanes
datacite.subjectLong Chains
datacite.subjectMacrocycles
datacite.subjectSolventless
datacite.subjectPositive Ions
datacite.subjectAlkyl Group
datacite.subjectBenzaldehyde
datacite.subjectBenzaldehyde Derivative
datacite.subjectMacrocyclic Compound
datacite.subjectAdult
datacite.subjectArticle
datacite.subjectCatalysis
datacite.subjectControlled Study
datacite.subjectDrug Analysis
datacite.subjectHydrolysis
datacite.subjectMale
datacite.subjectNonhuman
datacite.subjectOxidation
datacite.titleTwo-step access to bis-meso-perfluoroalkyl-corroles towards meso-perfluoroacyl-ABC-corroles
dc.contributor.authorSANHUEZA FRIGOLETT, JUAN MANUEL
dc.description.abstractA solventless and acid-catalyzed condensation of meso-perfluoroalkyl-dipyrromethanes with selected benzaldehydes was used to prepare ten different bilanes that were isolated before their oxidation into trans-A<inf>2</inf>B-corroles bearing two meso-perfluoroalkyl groups. Macrocycles bearing long chains (C<inf>3</inf>F<inf>7</inf> or C<inf>7</inf>F<inf>15</inf>) are key precursors to afford ABC-corroles having a meso-acyl substituent when subjected to a mild and basic hydrolysis affecting one of the alkyl substituents. © 2024 Elsevier B.V., All rights reserved.
dc.description.ia_keywordmeso, corroles, perfluoroalkyl, bearing, solventless, acid, catalyzed
dc.formatPDF
dc.identifier.issn1477-0520
dc.identifier.urihttps://repositoriodigital.uct.cl/handle/10925/5797
dc.language.isoen
dc.publisherRoyal Society Of Chemistry
dc.relationinstname: ANID
dc.relationreponame: Repositorio Digital RI2.0
dc.rights.driverinfo:eu-repo/semantics/openAccess
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/3.0/cl/
dc.sourceOrganic and Biomolecular Chemistry
dc.type.driverinfo:eu-repo/semantics/article
dc.type.driverhttp://purl.org/coar/resource_type/c_2df8fbb1
dc.type.openaireinfo:eu-repo/semantics/publishedVersion
dspace.entity.typePublication
oaire.citationEdition2024
oaire.citationEndPage1997
oaire.citationIssue10
oaire.citationStartPage1993
oaire.citationTitleOrganic and Biomolecular Chemistry
oaire.citationVolume22
oaire.fundingReferenceANID ECOS-SUD C19E07
oaire.fundingReferenceMESRI Francia
oaire.fundingReferenceMEAE Francia
oaire.fundingReferenceCNRS Francia
oaire.fundingReferenceANID FONDECYT 11181187, 1210355
oaire.fundingReferenceANID FONDEQUIP EQM180180
oaire.licenseConditionObra bajo licencia Creative Commons Atribución 4.0 Internacional
oaire.licenseCondition.urihttps://creativecommons.org/licenses/by/4.0/
oaire.resourceTypeArtículo
oaire.resourceType.enArticle
relation.isAuthorOfPublicatione9afcfba-e767-447c-9c5b-9e98d0f12944
relation.isAuthorOfPublication.latestForDiscoverye9afcfba-e767-447c-9c5b-9e98d0f12944
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uct.comunidadRecursos Naturalesen_US
uct.departamentoDepartamento de Ciencias Biológicas y Químicas
uct.facultadFacultad de Recursos Naturales
uct.indizacionScience Citation Index Expanded ? SCIE
uct.indizacionScopus
uct.indizacionMEDLINE
uct.indizacionPubMed
uct.indizacionChemical Abstracts Service (CAS)
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