Electron-donor substituents on the dppz-based ligands to control luminescence from dark to bright emissive state in Ir(III) complexes
Electron-donor substituents on the dppz-based ligands to control luminescence from dark to bright emissive state in Ir(III) complexes
Authors
Dreyse, Paulina
Santander-Nelli, Mireya
Zamorano, David
Rosales, Luis
Sanhueza, Luis
Santander-Nelli, Mireya
Zamorano, David
Rosales, Luis
Sanhueza, Luis
Authors
Date
Datos de publicaciĆ³n:
10.1002/qua.26167
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Abstract
The structures and electronic properties of a series of cyclometalated Ir(III) complexes with substituted dppz ancillary ligand (dppz: dipyrido[3,2-a:2 ',3 '-c]phenazine) including tert-butyl, pyrrolidine ring, and alkoxys substituents as donor group have been theoretically study. With the aim of highlight the attractive qualities of each system for their use as luminescent material, the effects of the electron-donor substituents onto dppz was evaluated on the structural, charge transport, absorption, and phosphorescent properties. The effect of the substituent was studied on the modulation of the bright and dark triplet states. Main results show that ortho-methoxy and tert-butyl substituents act as lower electron-donating groups, then, efficient electron donation ability was displayed with alkoxy (ethoxy and propoxy) substituents. The best performance was found in a complex with pyrrolidine ring according since their phosphorescence is favored, highlighting their larger electric transition dipole moment value, proposing this system as potential candidate to LEC technology.