Synthesis of a new polypyridinic highly conjugated ligand with electron-acceptor properties

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Autor:
Díaz Harris, Ramiro - Reyes, O. - Francois Cifuentes, María Angélica - Leiva, M.A. - Loeb, B.
URI:
https://hdl.handle.net/10925/720
Carrera:
Ingeniería en Recursos Naturales Renovables
Facultad:
Facultad de Recursos Naturales
Fecha de publicación:
2012-02-24
Datos de publicación:
Tetrahedron Letters, Vol. 42, N°37, 6463-6467, 2001
Temas:
Química
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Resumen:
A new acceptor polypyridinic ligand functionalized with a quinone fragment is reported. The ligand, dipyrido[3,2-a:2′,3′-c]-benzo[3,4]-phenazine-11,16-quinone, Nqphen, was synthesized by condensation of 1,10-phenanthroline-5,6-dione and 2,3-diamino-1,4-naphthoquinone. The syntheses of two rhenium complexes with this ligand are also reported.

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