Synthesis of a new polypyridinic highly conjugated ligand with electron-acceptor properties
- Autor:
- Díaz Harris, Ramiro - Reyes, O. - Francois Cifuentes, María Angélica - Leiva, M.A. - Loeb, B.
- URI:
- https://hdl.handle.net/10925/720
- Carrera:
- Ingeniería en Recursos Naturales Renovables
- Facultad:
- Facultad de Recursos Naturales
- Fecha de publicación:
- 2012-02-24
- Datos de publicación:
- Tetrahedron Letters, Vol. 42, N°37, 6463-6467, 2001
- Temas:
- Química
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- Resumen:
- A new acceptor polypyridinic ligand functionalized with a quinone fragment is reported. The ligand, dipyrido[3,2-a:2′,3′-c]-benzo[3,4]-phenazine-11,16-quinone, Nqphen, was synthesized by condensation of 1,10-phenanthroline-5,6-dione and 2,3-diamino-1,4-naphthoquinone. The syntheses of two rhenium complexes with this ligand are also reported.
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